I haven't done any full ships in sketchup myself - just extruded a few deckplans for fun - Ian had some cool 3D exterior/interiors of a cutter and a few other ships I think, including a very nice Scout. However, I think he found them too much work - but comment/email at his site.
Aramis had a ship (cutter?) or two in progress here at one time, IIRC.
Decades ago I made wireframe ships (custom coded before the days of OpenGL) - calculating volume then filling with 2D deckplan slices. I also did a few using CSG and POVRay which were very accurate - and very time consuming (again coded, no interactive 3D/GUI). I think Sketchup will give you volumes pretty easily. Think it helps to rough it out first based on primitive shapes. Refine till the exterior is complete. Then use section (IIRC) and lay in the deckplans and/or volumes (I'd 2D and extrude) - taking advantage of fuel dtons in awkward spaces.
Note - Sketchup does not really do curves well and it isn't a solid modeller (nor very parametric). If you want to work with curved surfaces - learn the basics (how/limits of Sketchup),
then grab some of the really great plugins at
http://sketchucation.com/forums/viewtopic.php?p=250026 (Fredo's are some of my favorites).
Also, when dealing with curves remember that once set, curves, like everything else, are just collections of faces made of lines and vertices. I.e. not solids and not editable as curves (directly). Picking the right number of segments is extremely important - helps to know your highest target scale (I.e. - if you plan to view/print a deckplan square at a certain RW unit size - like 1/2" = 1.5 meters). Right after creation you can easily change the number of segments, but later, especially when connected to other geometry, its a real PITA.
[I'm assuming you are using the free version - the $$$ version has boolean ops and lots of other nice features.]
Sketchup's modelling method is hard to beat, but if Blender ever gets some decent CAD features (IIRC, 2.49 had a BlenderCAD project - but newer versions broke its foundation), it would make a great starship modeling+deckplanning tool.