I was thinking about a world without natural uranium deposits - a world which usually has to import fissile material. So once interstellar trade declines (Hard Times), they won't have much fuel to run the reactors in the first place - so they'll start cannibalizing nukes.
They'd have some trouble with the weapons approach if they have no natural uranium, because what's done currently is to take the highly enriched uranium from weapons (usually 20-90% U-235, the rest U-238) and mix it with ordinary mined uranium (0.71% U-235 and 99.29% U-238) to end up with regular fuel rods (2-5% U-235, rest U-238). Sometimes they'll use plutonium in place of the U-235, making the MOX fuel as I noted earlier.
So if they've no source of uranium ore, then their only U-238 to mix the weapons material with is spent fuel rods. So then they get into having to reprocess those, and that's a very dirty business, you need heaps of chemicals and produce a large volume of radioactive waste (instead of a small volume of very radioactive waste, ie spent fuel rods, they have a large volume of somewhat radioactive waste, ie acids used in the thing, etc).
World stockpiles of weapons-grade plutonium are around, if I recall correctly, 250 tonnes. If every one of the 450 or so reactors in the world were adjusted to use MOX, it'd keep them going for a year or so. The Russians have got 500 tonnes of highly-enriched uranium which if blended with ordinary uranium could make about 15,000 tonnes of fuel rods, equivalent to about 150,000 tonnes of ordinary uranium - and the world currently uses about 66,000 tonnes annually.
So basically all these decommissioned Russian and US weapons, about 10,000 of them, plus stockpiled material for another 20,000, give you 30 months or so... and that's with about a sixth of world electricity use coming from nuclear - or all the electricity for 1 billion people. So you could make a rule of thumb that each 1,000 nuclear weapons will make electricity for 1 billion people for one month. Or 1 nuclear weapon for 1 million people for one month - though naturally the approximation doesn't hold for under 20 or so nukes, since reactors have 18 month fuel cycles.
Basically, it's as I said - the mass of stuff going through the power plants is just huge compared to what you need even for an utterly insane number of nuclear weapons.
There also exist "breeder" reactors, basically the idea is to work hard to turn the U-238 into Pu-239. They're pretty difficult to make work very well, but potentially they could essentially triple the longevity of your uranium supply.
There also thorium reactor designs, but presumably if your planet has no uranium it'll have no thorium, either. And anyway thorium reactors need plutonium as a sort of seed - about as much as is needed for a weapon, by coincidence...
So I can't really see weapons as fuel as more than a stopgap measure for a place with no natural uranium source. They'd have to drastically reduce their electricity use, or else just use the method to buy time while working on some other method of power generation like solar.
Though of course there could be exceptions, like if you had some asteroid mining and naval base powered by a reactor and absolutely loaded with nukes... though they'd need some snazzy labs and factories for it all.