Thematically, I've found that Traveller is big on stuff being preserved for far longer that I would think realistic. People salvaging RFX guns from destroyed Trepida tanks on habitable worlds after 70 years and so on.
There's a few culprits for this kind of stuff but it mostly revolves around access to oxygen and energy. Extremes of temperatures are obviously bad for equipment unless it was designed for it, but just as bad are seasonal or even daily temperature variances over a long period of time - all that thermal expansion and contraction will take its toll, multipled over long years.
Using your example of a PGMP-14, if a trooper carrying it is on a temperate habitable world and he gets cacked and drops it in the underbrush, I'd say there's no chance of it being in working condition (let alone the fact that I'd find it unlikely that nobody else would pick it up in the meanwhile). If it was kept in an underground bunker in a locker, it might survive a bit better. Like a bunker on a world with low humidity away deep in the stone? It might still be in workable condition.
On the other hand, stuff can survive in places where it seems singularly unlikely, like saltwater immersion for centuries - like if the gun is buried in oxygen-poor sediments in cold water, it might be in surprisingly good shape (perhaps not firable but certainly not a complete loss).
If you're looking to add a bit of 'flavor' to salvaging weapons and such, I'd break a PGMP into, say, three components grouped by fragility. These can be particular "vulernable" spots. Like one would be the weapon 'overall' (everything not covered by anyhting else). The second might be magneto-optic array and ammunition. The third would be "the PFC44 Plasma Focusing Array, a notoriously finicky item on the otherwise very solid standard PGMP-14s - of all relic plasma guns its been found that PFC44 failure is responsible for a full 60% of the unfirable weapons in the hands of TEDs and their troops (and was part that required precision computer-controlled machining tooled for micron tolerances). While in 1108 there was a redesign of the part to the PFC44-1108 standard which was much simplier and reliable, retooling and introduction of the new coupling was slow and most units not part of the Household Cavalry or those in Iliesh only had spotty access to the new parts."
EDIT: I guess I should finish this post.
The thought would be after you break the item down into three component areas, make checks for failures from the "top down." If you fail one roll, don't go on to the next. So if you fail on the first roll, the gun is a total loss for whatever reason, be it rusted, partially/totally bent/twisted/melted, a home for a thriving colony of insects and molds, or whatever. If you fail the second roll, the weapon would be unusable (but could be returned to service) and/or could be used to scavenge spare parts and some of the ammunition might still be good. With the third, the weapon is basically servicable, but you'd have to replace the particular finicky part. If you make all three rolls, the weapon is perfectly fine.